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41.
Impact of a Stereocentre Inversion in Cyclic Lipodepsipeptides from the Viscosin Group: A Comparative Study of the Viscosinamide and Pseudodesmin Conformation and Self‐Assembly 下载免费PDF全文
Niels Geudens Matthias De Vleeschouwer Dr. Krisztina Fehér Dr. Hassan Rokni‐Zadeh Dr. Maarten G. K. Ghequire Prof. Dr. Annemieke Madder Prof. Dr. René De Mot Prof. Dr. José C. Martins Dr. Davy Sinnaeve 《Chembiochem : a European journal of chemical biology》2014,15(18):2736-2746
The viscosin group covers a series of cyclic lipodepsipeptides (CLPs) produced by Pseudomonas bacteria, with a range of biological functions and antimicrobial activities. Their oligopeptide moieties are composed of both L ‐ and D ‐amino acids. Remarkably, the Leu5 amino acid—centrally located in the nonapeptide sequence—is the sole residue found to possess either an L or D configuration, depending on the producing strain. The impact of this D /L switch on the solution conformation was investigated by NMR‐restrained molecular modelling of the epimers pseudodesmin A and viscosinamide A. Although the backbone fold remained unaffected, the D /L switch adjusted the segregation between hydrophobic and hydrophilic residues, and thus the amphipathicity. It also influenced the self‐assembly capacity in organic solvents. Additionally, several new minor variants of viscosinamide A from Pseudomonas fluorescens DR54 were identified, and an NMR assay is proposed to assess the presence of either an L ‐ or D ‐Leu5. 相似文献
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This paper focuses on the design of time-homogeneous fully observed Markov decision processes (MDPs), with finite state and action spaces. The main objective is to obtain policies that generate the maximal set of recurrent states, subject to convex constraints on the set of invariant probability mass functions. We propose a design method that relies on a finitely parametrized convex program inspired on principles of entropy maximization. A numerical example is provided to illustrate these ideas. 相似文献
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Clemente Neves Sousa Paulo Teles Vanessa Filipa Ferreira Dias João Luís Alves Apóstolo Maria Henriqueta Jesus Silva Figueiredo Maria Manuela Martins 《Hemodialysis international. International Symposium on Home Hemodialysis》2014,18(3):695-699
Vascular access is one of the leading causes of mobilization of financial resources in health systems for people with chronic kidney disease on hemodialysis. Physical examination of the arteriovenous fistula (AVF) has demonstrated its effectiveness in identifying complications. We decided to evaluate the influence of nurses' professional experience in the detection of complications of the AVF (venous stenosis and steal syndrome). The study took place in eight hemodialysis centers between May and September of 2011 in the north of Portugal. Sample was constituted by registered nurses. The nurses involved in the experiment were divided in two groups: those who had more than 5 years of experience and those who had less than 5 years of experience. Ninety‐two nurses participated in the study: 34 nurses had less than 5 years of professional experience and 58 had more than 5 years of professional experience. In the practices considered by nurses in the detection of venous stenosis, there were no differences observed between the groups (P > 0.05). In steal syndrome, there were no differences observed between the groups in the practices of the nurses in the detection of this complication of the AVF (P > 0.05). We concluded that professional experience does not influence the detection of venous stenosis and steal syndrome. 相似文献
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Marcos Eduardo Valle Raul Ambrozio Valente 《Journal of Mathematical Imaging and Vision》2017,57(2):183-201
Mathematical morphology is a theory with applications in image processing and analysis. This paper presents a quantale-based approach to color morphology based on the CIELab color space in spherical coordinates. The novel morphological operations take into account the perceptual difference between color elements by using a distance-based ordering scheme. Furthermore, the novel approach allows for the use of non-flat structuring elements. An illustrative example reveals that non-flat dilations and erosions may preserve more features of a color image than their corresponding flat operations. Furthermore, the novel non-flat morphological operators yielded promising results on experiments concerning the detection of the boundaries of objects on color images. 相似文献
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Lucas Oliveira Rodrigues Marcos Martins Gouvêa Flávia Ferreira de Carvalho Marques Samanta Cardozo Mourão 《Scientometrics》2017,110(3):1157-1171
In Brazil, the National Council for Scientific and Technological Development (CNPq) distributes productivity fellowships in research (RS) as a recognition to individuals with outstanding productivity levels in their areas. The aim of this study is to evaluate the scientific production of the Brazilian Pharmacy area, one division of the Health Sciences Great Area of CNPq, considering the profile and productivity levels of RS fellows. The results showed that most of the 156 active RS fellows in 2015 were female, with doctorate completed in the Southeast region (mainly in University of São Paulo) and with research activities developed in the South and Southeast regions. Most of their work was published in journals classified as B1 and B2 Qualis in Pharmacy by the Coordination for the Improvement of Higher Education Personnel (CAPES), with high prevalence of publications in local journals and/or specialized on medicinal plants. Besides, they featured much dependence on advising and productivity indexes related to the category and level of RS fellowship. The evolution of such data must be continually evaluated to determine the influence of CNPq productivity fellowships on performance and stratification of researchers in the Pharmacy area in Brazil. 相似文献
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Front Cover: Photoactivatable Mussel‐Based Underwater Adhesive Proteins by an Expanded Genetic Code (ChemBioChem 18/2017) 下载免费PDF全文
Dr. Matthias Hauf Dr. Florian Richter Tobias Schneider Thomas Faidt Dr. Berta M. Martins Dr. Tobias Baumann Dr. Patrick Durkin Prof. Dr. Holger Dobbek Prof. Dr. Karin Jacobs Prof. Dr. Andreas Möglich Prof. Dr. Nediljko Budisa 《Chembiochem : a European journal of chemical biology》2017,18(18):1771-1771